|
|
3''-phosphoadenylyl-sulfate + desulfo-indol-3-yl-methyl_glucosinolate <=> adenosine_3,5''-bisphosphate + glucobrassicin + H+
|
2.8.2.24
aromatic desulfoglucosinolate sulfotransferase
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
BRENDA:
BR52177;
BS407937
KEGG:
R08167
MetaCyc:
RXN-1443
|
|
|
|
S-adenosyl-L-methionine + 1-hydroxyglucobrassicin <=> neoglucobrassicin + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-2161
|
|
|
|
S-adenosyl-L-methionine + 4-hydroxyglucobrassicin <=> 4-methoxyindol-3-ylmethyl-glucosinolate + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-2163
|
|
|
|
glucobrassicin + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1-hydroxyglucobrassicin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-18166
|
|
|
|
H+ + N,N-dihydroxy-L-tryptophan <=> (E,Z)-indolyl-3-acetaldoxime + CO2 + H2O
|
1.14.14.156
tryptophan N-monooxygenase
|
–
|
| |
BRENDA:
BR49596
KEGG:
R09585
MetaCyc:
RXN-12063
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-2-(1H-indol-3-yl)ethan-1-imine + H2O <=> H+ + 2-(3-indolyl)acetothiohydroximate + L-seryl-glycine
|
4.4.1.M2
|
–
|
| |
MetaCyc:
RXN-11437
|
|
|
|
L-tryptophan + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N-hydroxy-L-tryptophan + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-12061
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-2-(1H-indol-3-yl)ethan-1-imine + H2O <=> (E)-1-(L-cystein-S-yl)-N-hydroxy-2-(1H-indol-3-yl)ethan-1-imine + glycine
|
3.4.13.23
cysteinylglycine-S-conjugate dipeptidase
|
–
|
| |
MetaCyc:
RXN-19594
|
|
|
|
N-hydroxy-L-tryptophan + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N,N-dihydroxy-L-tryptophan + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-12062
|
|
|
|
1-aci-nitro-2-indolyl-ethane + glutathione <=> (E)-1-(glutathion-S-yl)-N-hydroxy-2-(1H-indol-3-yl)ethan-1-imine + H2O
|
1.14.14.45
aromatic aldoxime N-monooxygenase
|
–
|
| |
BRENDA:
BR52038
KEGG:
R11736
MetaCyc:
RXN-11421
|
|
|
|
glucobrassicin + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 4-hydroxyglucobrassicin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.13.M51
|
–
|
| |
MetaCyc:
RXN-2162
|
|
|
|
(E)-1-(glutathion-S-yl)-N-hydroxy-2-(1H-indol-3-yl)ethan-1-imine + H2O <=> (E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-2-(1H-indol-3-yl)ethan-1-imine + L-glutamate
|
3.4.19.16
glucosinolate gamma-glutamyl hydrolase
|
–
|
| |
BRENDA:
BR52188
KEGG:
R11793
MetaCyc:
RXN-11429
|
|
|
|
(E)-1-(L-cystein-S-yl)-N-hydroxy-2-(1H-indol-3-yl)ethan-1-imine + H2O <=> 2-(3-indolyl)acetothiohydroximate + pyruvate + NH3 + H+
|
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
|
| |
MetaCyc:
RXN-19586
|
|
|
|
UDP-glucose + 2-(3-indolyl)acetothiohydroximate <=> desulfo-indol-3-yl-methyl_glucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
BRENDA:
BR52366
KEGG:
R08164
MetaCyc:
RXN-1442
|
|
|
|
(E,Z)-indolyl-3-acetaldoxime + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 1-aci-nitro-2-indolyl-ethane + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11413
|
|
